| CHARNOCK, Gemma Claire ACTIVE | Secretary | 24 Jul 2014 | | | | Neath Port Talbot College, Dwr Y Felin Road, Neath, West Glamorgan, SA10 7RF |
| DACEY, Mark ACTIVE | Director | 26 Aug 2011 | | Wales | August 1961 | Neath Port Talbot College, Dwr Y Felin Road, Neath, SA10 7RF, United Kingdom |
| EVANS, Mandy ACTIVE | Director | 07 Oct 2011 | | United Kingdom | September 1964 | Neath Port Talbot College, Dwr Y Felin Road, Neath, West Glamorgan, SA10 7RF, United Kingdom |
| HARVEY, Matthew James Richard ACTIVE | Director | 17 Jul 2024 | | Wales | August 1980 | Neath Port Talbot College, Dwr Y Felin Road, Neath, West Glamorgan, SA10 7RF |
| LEWIS, Catherine Anne ACTIVE | Director | 25 Jan 2013 | | Wales | December 1969 | Neath Port Talbot College, Dwr Y Felin Road, Neath, West Glamorgan, SA10 7RF, United Kingdom |
| THORNTON-SCOTT, Nicola Karen ACTIVE | Director | 07 Oct 2011 | | Wales | November 1962 | Neath Port Talbot College, Dwr Y Felin Road, Neath, West Glamorgan, SA10 7RF, United Kingdom |
| DOYLE, Terrence Patrick RESIGNED | Secretary | | 26 Aug 2011 | | | 7 Penllech, Pwll, Llanelli, Dyfed, SA15 4AN |
| LARCHER, Raine Margaretta RESIGNED | Secretary | 26 Aug 2011 | 30 Sep 2013 | | | Neath Port Talbot College, Dwr Y Felin Road, Neath, SA10 7RF, United Kingdom |
| BOOKER, Keith Robert RESIGNED | Director | 17 Jun 2016 | 31 Dec 2017 | Wales | October 1956 | Neath Campus, Dwr Y Felin Road, Neath, Neath Port Talbot, SA10 7RF, Wales |
| DOODSON, Stephen Peter RESIGNED | Director | 30 Sep 2015 | 14 Sep 2016 | Wales | May 1960 | Neath Port Talbot College, Dwr Y Felin Road, Neath, West Glamorgan, SA10 7RF |
| EDWARDS, Irene Ann RESIGNED | Director | 25 Sep 2009 | 26 Aug 2011 | Wales | April 1947 | 29, Hendre Park, Llangennech, Llanelli, Carmarthenshire, SA14 8UP |
| FOUNTAIN, Kelly Ann RESIGNED | Director | 07 Oct 2021 | 14 Dec 2023 | Wales | March 1979 | Neath Port Talbot College, Dwr Y Felin Road, Neath, West Glamorgan, SA10 7RF |
| FOWLER, Robert Gwyn RESIGNED | Director | 10 Feb 2012 | 21 Jun 2012 | United Kingdom | May 1953 | Neath Port Talbot College, Dwr Y Felin Road, Neath, West Glamorgan, SA10 7RF, United Kingdom |
| FRANCIS, Thomas Rhys RESIGNED | Director | | 16 Apr 2007 | | October 1926 | Ty Twt Meinciau Road, Mynyddygarreg, Kidwelly, Dyfed, SA17 4RA |
| HITCHINGS, Roger Michael RESIGNED | Director | 11 Apr 1994 | 22 Jun 2018 | Wales | May 1945 | The Dower House, Glyn Abbey, Llanelli, Dyfed, SA15 5TL |
| HOLLEY, Kathryn Geraldine RESIGNED | Director | 26 Aug 2011 | 14 Jun 2024 | United Kingdom | November 1974 | Neath Port Talbot College, Dwr Y Felin Road, Neath, SA10 7RF, United Kingdom |
| JACKMAN, Timothy Stephen RESIGNED | Director | | 21 May 1993 | | April 1955 | 10 Castle Street, Kidwelly, Dyfed, SA17 5AX |
| MEARS, Steven Royston RESIGNED | Director | 25 Sep 2009 | 26 Aug 2011 | Wales | August 1962 | 1, Llys Cilsaig, Dafen, Llanelli, Carmathenshire, SA14 8QT |
| PHILLIPS, David Marc RESIGNED | Director | | 20 Nov 2012 | United Kingdom | December 1953 | 31 Mafeking Road, Cardiff, South Glamorgan, CF23 5DQ |
| RAYNER, Bryan Joseph RESIGNED | Director | | 27 Mar 1992 | | July 1936 | 130 Elkington Road, Burry Port, Dyfed, SA16 0AD |
| RICHARDS, MBE, Gaynor Marie RESIGNED | Director | 26 Aug 2011 | 07 Oct 2011 | United Kingdom | January 1955 | Neath Port Talbot College, Dwr Y Felin Road, Neath, SA10 7RF, United Kingdom |
| TYLER, Julian Anthony RESIGNED | Director | 26 Aug 2011 | 31 Dec 2013 | United Kingdom | May 1956 | Neath Port Talbot College, Dwr Y Felin Road, Neath, SA10 7RF, United Kingdom |